Diew Saijun, Charoen Nakason, Azizon Kaesaman, and Pairote Klinpituksa

pp. 561 - 565

Abstract

Water-swellable rubber (WSR) was prepared by blending superabsorbent polymer (SAP) of crosslinked poly (acrylamide-co-sodium acrylate) with natural rubber in latex condition. The crosslinked poly(acrylamide-co-sodium acrylate) was first prepared by inverse suspension polymerization from acrylamide and sodium acrylate monomers with potassium
persulfate initiator and N,N′-methylenebisacrylamide crosslinker. The reaction was carried out at 60°C for 40 mins. Water absorption properties, such as the degree of water absorption, water absorption rate, degree of weight loss, and mechanical properties of WSR were then investigated. It was found that the degree of water absorption, water absorption rate, and the degree of weight loss increased, while tensile strength and elongation at break decreased with increasing quantity of SAP in the blends. However, the degree of water absorption, degree of weight loss, and elongation at break decreased, but tensile strength increased with increasing quantity of the N-tert-butyl-2-benzothiazyl sulphenamide (TBBS) accelerator used in the compounds formulation.