Original Article |
2013, Vol.35, No.6, pp. 727-738
Evaluation of carbaryl sorption in alluvial soil
Naba Kumar Mondal, Soumya Chattoraj, Bikash Sadhukhan, and Biswajit Das
pp. 727 - 738
Abstract
This study investigated the adsorption potential of carbaryl onto alluvial soil. Parameters that influence the adsorption process such as pH, adsorbent dose, initial carbaryl concentration, stirring rate, particle size, contact time and temperature were studied in a batch process. The carbaryl adsorption capacity was at maximum at pH 6 for an initial concentration of 20 ppm. Adsorption equilibirium time was observed in 180 min. Equilibrium adsorption data was best fitted with Freundlich isotherm and pseudo-first order kinetic model, respectively. The adsorbent was characterized by X-ray diffraction spectrum, Fourier transform infrared spectroscopy and scanning electron microscopy. The experiment performed indicated that the adsorption capacity of carbaryl was significantly correlated with particle size, organic matter and pH of the soil. Therefore, the possibility for carbaryl to contaminate underground water may be greater in the presence of low organic matter content.